Superkapasitor Dari Karbon Aktif Limbah Daun Teh Sebagai Bahan Elektroda

Authors

  • Nani Kurniawati
  • Tri Surawan

DOI:

https://doi.org/10.31479/jtek.v8i1.64

Abstract

Superkapasitor merupakan teknologi baru yang menjanjikan sebagai perangkat penyimpan energi listrik di masa depan . Hal ini dikarenakan bahan baku mudah didapat, murah harganya dan proses pembuatannya relatif sederhana. Elektroda superkapasitor yang berasal dari limbah daun teh sebagai  bahan karbon aktif memiliki kemampuan daya dan energi yang tinggi karena memiliki luas permukaan yang tinggi, konduktivitas tinggi, dan kemampuan karbon aktif untuk mengoptimalkan sifat superkapasitornya. Pengaruh metoda aktivasi, jenis aktivator, jenis elektrolit, proses karbonasi atau pirolisis yang digunakan akan menentukan daya dan kerapatan energi yang dihasilkan oleh superkapasitor. Dalam hal ini juga ditinjau proses pembentukan lapisan rangkap listrik pada permukaan elektroda dan pengaruh jenis elektrolit yang digunakan terhadap kinerja superkapasitor. Penelitian ini melalui beberapa tahap al : Persiapan bahan baku ( Limbah dan teh ), pengeringan dengan oven  T 700 C waktu 2 jam menghasilkan arang karbon dilanjutkan penggilingan, terakhir aktivasi dengan larutan KOH 3M dan 5M. Superkapasitor dari bahan limbah daun teh yang diaktivasi dengan KOH 3M memiliki kapasitansi sebesar 5,45 Farad dan yang diaktivasi dengan KOH 5M memiliki kapasitansi sebesar 11,8 Farad.

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References

Z. Zhu, H. Hu, W. Li and X. Zhang , "Resorcinol Formaldehyde Based Porous Carbon as an Electrode Material for Supercapacitors," J.Carbon, vol. 45, no. 1, pp. 160-165, 2007.

K. H. An, W. S. Kim, Y. S. Park and Y. C. Choi, "Supercapacitors Using Single-Walled Carbon Nanotube Electrodes," Adv, Mater, vol. 13, no. 7, pp. 497-500, 2001.

A. K. Shukla, S. Sampath and K. Vijayamohanan, "Electrochemical Supercapacitors: Energy Storage Beyond Batteries," Current Science, vol. 79, no. 12, pp. 1656 - 1661, 2000.

T. Surawan and P. S. Priambodo, "Supercapacitor Based On Active Carbon Electrode," in 6th International Conference on Quality in Research (QIR): International Symposium on Electrical and Computer Engineering, 2019.

K. Mensah-Darkwa, P. K. Kahol, R. K. Kahol, and S. Bhoyate, "Recent Development on Nanocomposites of Graphene for Supercapacitor Applications," Current Graphene Science, vol. 1, no. 1, pp. 26-43, 2017.

S. D. Dietz and Nguyen, "Mesoporous Carbon Electrodes for Double Layer Capacitors," in Service and Manufacturing Grantees and Research Conference, Tampa, 2002.

Z. Zhu, H. Hu, W. Li and X. Zhang , "Resorcinol Formaldehyde Based Porous Carbon as an Electrode Material for Supercapacitors," J.Carbon, vol. 45, no. 1, pp. 160-165, 2007.

N. R. Khalili, M. Campbell, G. Sandi and Golas, "Production of Micro- and Mesoporous Activated Carbon from Paper Mill Sludge; Effect of Zinc Chloride Activation," Carbon, vol. 38, no. 1, pp. 1905-1915, 2000.

L. Zhang, H. Liu , M. Wang and L. Chen, "Structure and Electrochemical Properties of Resorcinol–Formaldehyde Polymer-Based Carbon for Electric Double-Layer Capacitors," Carbon, vol. 45, no. 1, pp. 1439-1445, 2009.

K. Lenghaus, G. G. Qiao, D. H. Solomon and C. Gomez, "Controlling Carbon Microporosity: The Structure of Carbons Obtained from Different Phenolic Resin Precursors," Polymer Science Group, vol. 40, no. 5, pp. 743-749, 2001.

L. Yueming, Z. M. van , S. Chiang S and N. Pan , "KOH Modified Graphene Nanosheets for Supercapacitor Electrodes," Journal of Power Sources, vol. 196, no. 1, pp. 6003-6006, 2011.

M. Zuleta , P. Bjornbom and A. Lundblad , "Effects of Pore Surface Oxidation on Electrochemical and Mass-Transport Properties of Nanoporous Carbon," Journal of The Electrochemical Society, vol. 152, pp. 270-276, 2005.

V. Ruiz, C. Blanco, M. Granda and R. Menender, "Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors," J Appl Electrochem, vol. 37, pp. 717-712, 2007.

J. Mi, X. R. Wang, R. J. Fan, W. H. Qu and W. C. Li, "Coconut-shell-based porous carbons with a tunable micro/mesopore ratio for high-performance supercapacitors," Energy Fuels, vol. 26, p. 5321–5329., 2012.

L. Yin, Y. Chen, D. Li , X. Zhao, B. Hou and Cao, "3-Dimensional hierarchical porous activated carbon derived from coconut fibers with high-rate performance for symmetric supercapacitors," J. Mater, vol. 111, p. 44–50, 2016.

W. H. Qu, Y. Y. Xu, A. H. Lu, X. Q. Zhang and Li, "Converting biowaste corncob residue into high value added porous carbon for supercapacitor electrodes," Bioresour. Technol, vol. 189, p. 285–291, 2015.

M. Fu, W. Chen, X. Zhu , B. Yang and Q. Liu, "Crab shell derived multi-hierarchical carbon materials as a typical recycling of waste for high performance supercapacitors," J.Carbon, vol. 141, pp. 748-757, 219.

A. E. Ismanto , S. Wang, F. E. Soetaredjo and F. E. Ismadji, "Preparation of capacitor’s electrode from cassava peel waste," Bioresour. Technol., vol. 101, p. 3534–3540., 2010.

H. Aripin , . L. Lestari, D. Ismail and S. Sabchevski , "Sago Wasted Based Activated Carbon Film as an Electrode Material for Electric Double Layer Capacitor," The Open Materials Science Journal, vol. 4, pp. 117-124, 2010.

R. L. Tseng and R. K. Tseng , "Pore structure and adsorption performance of the KOH Activated Carbon Prepared from Corncob," J Coloid Interf Science, vol. 287, pp. 428-37, 2005.

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Published

2020-12-04